PST time changing tonight, I am not sure if this is going to affect the database....
IF you are up-to-date on your TZ files the database itself should be fine. But external processing is another matter - especially if you have processes that assume conventions from previous PG versions. For example:
PG 7.4 (one day = 24 hours): select now();
now ------------------------------- 2009-03-09 12:05:42.533139-07
That's just in the database itself and without cross-country processing (i.e.: if you have somewhat synchronized processes that assume that New York is 3 hours ahead of San Francisco you can have problems if you don't consider that New York changed to DST 3 hours ahead of San Francisco).
Then there are the scripts that calculate dates externally for feeding into your database-backed processes (for fun, try "-d yesterday" and "-d tomorrow" in most versions of the "date" command in the vicinity of DST changes).