Just trying to read first row in table based on index, pg scans and sorts instead?

I populated my table, then added the following index. I want to read the
first row based on this index but it takes 3 seconds to get the result. I
hope there's a way to improve this, possibly take advantage of the index.

Index:
    "rx_storenbr_rxnbr_rfnbr_index" UNIQUE, btree (storenbr, rxnbr, rfnbr)



reports=> EXPLAIN ANALYZE SELECT * FROM rx ORDER BY (storenbr,rxnbr,rfnbr)
LIMIT 1;
                                                        QUERY PLAN

---------------------------------------------------------------------------------------------------------------------------
 Limit  (cost=24935.26..24935.27 rows=1 width=828) (actual
time=3179.721..3179.721 rows=1 loops=1)
   ->  Sort  (cost=24935.26..25399.14 rows=185551 width=828) (actual
time=3179.719..3179.719 rows=1 loops=1)
         Sort Key: (ROW(storenbr, rxnbr, rfnbr))
         Sort Method: top-N heapsort  Memory: 18kB
         ->  Seq Scan on rx  (cost=0.00..24007.51 rows=185551 width=828)
(actual time=0.038..1094.316 rows=185551 loops=1)
 Total runtime: 3179.986 ms
(6 rows)

reports=>
reports=> select version();
                                               version
                                               
------------------------------------------------------------------------------------------------------
 PostgreSQL 9.1.2 on i686-pc-linux-gnu, compiled by gcc (Ubuntu/Linaro
4.4.4-14ubuntu5) 4.4.5, 32-bit
(1 row)





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